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Q.

Standard Gibb's energy of reaction (r ,G°) at a certain temperature car computed and as ΔTG=ΔΓHTΔrSand the change in the value of ΔrHand ΔrS for a reaction with temperature can be computed as follows: 

ΔrHT2ΔrHT1=ΔrCpT2T1ΔrST2ΔTST1=ΔrCplnT2T1ΔrG=ΔrHTΔrSand  by ΔG=RTlnKeq.

Consider the following reaction: CO(g)+2H2(g)CH3OH(g) 

Given :

ΔfHCH3OH,g=201kJ/mol;ΔfH(CO,g)=114kJ/molSCH3OH,g=240J/Kmol; SH2,g=29JK1mol1S(CO,g)=198J/molK; CpmH2=28.8J/molKCnm(CO)=29.4J/molK; C0,mCH3OH=44J/molK

 and ln320300=0.06, all data at 300K

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