Q.

Starting from 'a' mole of H2 and 'b' moles of I2 an equilibrium H2+I22HI is established with 2x moles of HI. The equilibrium constant KC is

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a

4x2(a-x)(b-x)

b

2x2(a-x)(b-x)

c

4x2(a-2x)(b-2x)

d

4x2ab

answer is B.

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Detailed Solution

 The reaction is given below,

H2+I22HI

For the above reaction,

At, t=0, H2= a and I2=b

At equilibrium, H2=a–x, I2=b–x and 2HI= 2x

So, KC=(2X)2(a-x)(b-x)

KC=4×2(a-x)(b-x)

Therefore, the correct answer is option (B) 4x2(a-x)(b-x).

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