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Q.

State and explain Dalton’s law of partial pressures.

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Detailed Solution

“The total pressure exerted by a mixture of non reacting gases is equal to the sum of the partial pressures of individual gases”.
P(Total )=P1+P2+P3+
P1,P2,P3 etc are partial pressures of gases.
Partial pressure in terms of mole fraction :
Suppose at the temperature T, three gases, enclosed in the volume V, exert partial pressure
P1, P2 and P3 respectively.
P1=n1RTVP2=n2RTV;P3=n3RTV
According to Dalton’s law
P=P1+P2+P3=n1RTV+n2RTV+n3RTV=n1+n2+n3RTVP=nRTV Where n=n1+n2+n3P1P=n1n=X1
X1 is called mole fraction of first gas.
P=XPTotal 

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