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Q.

State Bohr’s quantization condition of angular momentum. Calculate the shortest wavelength of the Bracket series and state to which part of the electromagnetic spectrum does it belong.
OR
Calculate the orbital period of the electron in the first excited state of hydrogen atom.

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Detailed Solution

According to Bohr’s quantization of angular momentum, the stationary orbits are those in which angular momentum of electron
is an integral multiple of h2πi.e.,
mvr=nh2π Where, n=1,2,3
For Brackett series,
1λmin=n=1sinC 1λmin=R16v=ze220nv=e220
Where,
R= Rydberg constant =1.096×107m1
      λmin    =161.096×107m    =14.599×107         =14599
Brackett series is found in infrared region 106Å to 7000 of electromagnetic spectrum.
OR
For hydrogen atom z=1 and n=1
Velocity of electron,
v=ze220nv=e220
Therefore, v=c137, where , c is velocity of light.
Orbital period 
= Distance  Velocity =2πrc×137=2×3.14×5.29×1011×1373×103=1.517×1016sec


 
 

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