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Q.

Statement - I : 2,2-Dimethylpropanal undergoes Cannizzaro reaction with conc. NaOH.
Statement - II : Cannizzaro reaction is a disproportionation reaction.

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is A.

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Detailed Solution

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Even though (CH3​)2​CH−CHO has α-hydrogen, it undergoes Cannizzaro reaction, due to + I effects of methyl group and easy transfer of H ion from one molecule to another.

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Statement - I : 2,2-Dimethylpropanal undergoes Cannizzaro reaction with conc. NaOH.Statement - II : Cannizzaro reaction is a disproportionation reaction.