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Q.

Statement - I : C–H bond length in acetylene is 1.06A0 and that in ethylene is 1.09A°.

Statement - II : C–H bond in acetylene is due to sp–s overlapping whereas in ethylene it is due to sp2 – s overlapping.

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a

Statement I and Statement II are false.

b

Statement I and Statement II are ture

c

Statement I is false and Statement II ture.

d

Statement I is ture and Statement II false.

answer is A.

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Detailed Solution

 

 

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As the % of s-character increases, spherical shape of hybridised orbital increases, hence closeness of orbital (or e-s) to the nucleus increases, ie., size of hybridised orbital decreases, hence C – H bond length decreases.

 

 

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