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Q.

Statement - I : Chlorine undergoes disproportionation reaction in alkaline medium
Statement - II : Cl₂ is an oxidising agent

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is B.

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Detailed Solution

Cl₂+2NaOH(dil.) $\overset{cold}{\to}$ NaCl+NaOCl+H2O
3Cl₂+6NaOH(conc.) $\overset{heat}{\to}$ 5NaCl+NaClO₃+3H₂O
Chlorine undergoes the simultaneous oxidation-reduction.
Chlorine is simultaneously reduced to chloride ion (Cl−) and is oxidized to either ClO⁻ or ClO₃⁻ ion.
Halogens (e.g. Cl) have a strong tendency to accept electrons, so they act as strong oxidizing agents.

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