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Q.

Statement - I : cis 3-chloroprop-2-enoic acid is less stable than its trans-form.
Statement - II : dipole moment of cis-form is greater than transform.

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is B.

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Detailed Solution

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Statement - I is true because usually, for acrylic systems trans-isomers are more stable than cis-isomers. This is due to increased unfavourable steric interaction of the substituents in cis-isomer. 

Statement - II  is also true because generally the dipole moment of trans-form is zero (or less) depending whether the substituents on both sides of double bond are same or not while cis-forms are polar in nature with certain value of dipole moment.

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