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Q.

Statement - I : Complexes containing ambidentate ligands exhibit co-ordination isomerism.
Statement - II : Co-ordination isomerism is shown by anionic complexes only.

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a

Statement-I is correct and statement-II is incorrect

b

Both statements I and II are correct

c

Statement-I is incorrect and statement-II is correct

d

Both statements I and II are incorrect

answer is D.

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Detailed Solution

  • If a complex contain an ambidentate ligand, it can show linkage isomerism.
  •  Thiocyanato (NCS) is such a ligand which can coordinate through two donor atoms.
  •  Hence, linkage isomerism is possible. 
  • Coordination isomerism occurs compounds containing complex anionic and cationic parts can be thought of as occurring by interchange of some ligands from the cationic part to the anionic part.
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