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Q.

Statement - I : Enthalpy of physical adsorption is lower than chemical adsorption
Statement - II : Molecule of adsorbate and adsorbent are held together by vanderwaal forces in physical adsorption and by chemical bonds in chemical adsorption

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is A.

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Detailed Solution

The enthalpy of chemisorption is of the order of 200 kJmol−1 while for physical adsorption it is of the order of 20 kJmol−1. Because molecules of adsorbate and adsorbent are held by van der Waals forces in physisorption and by chemical bonds in chemisorption.

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