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Q.

Statement - I : Formic acid reduces mercuric chloride to mercurous chloride on heating, while acetic acid does not.
Statement - II : Formic acid is a stronger acid than acetic acid.

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a

Both statements I and II are correct

b

Statement-I is correct and statement-II is incorrect

c

Statement-I is incorrect and statement-II is correct

d

Both statements I and II are incorrect

answer is B.

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Detailed Solution

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Formic acid behaves as reducing agent as it is oxidised to an unstable acid, carbonic acid, which decomposes into CO2 and H2O. Acetic acid remains unaffected by mercuric chloride, as it does not show reducing properties.

In acetic acid, methyl group is present which exerts +I effect and thus increases negative charge on the carboxylate ion and destabilise it. The loss of proton becomes comparatively difficult in comparison to formic acid. Hence, acetic acid is weaker acid than formic acid.

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Statement - I : Formic acid reduces mercuric chloride to mercurous chloride on heating, while acetic acid does not.Statement - II : Formic acid is a stronger acid than acetic acid.