Q.

Statement - I : One molar aqueous solution (d=1gm/cc) has always higher concentration than one molal.
Statement - II : The molality of a solution does not depends on temperature whereas molarity depends

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is A.

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Detailed Solution

consider 1 molal sol. of Glucose

  nsolute = 1  ,   Ws = 1(180) = 180g

  Wo =1000g

1 molal solution  means  1 mole solute present in 1000g of solvent

1 Molar solution  of Glucose:

                        ns =1 ,  Ws = 1(180) =180g

                        Vsol = 1000ml , dsol. =1g/cc

                         Wsol.  = 1000g, Wo = (1000-180) = 820g

1M sol. means 1 mole of solute in 820g of solvent

By comparing 1M & 1m sol. of Glucose,

1M sol. is more concentrated than 1m sol.

(ii) molality1Wsolvent

Wt. of substance is independent of Temperature

Molarity1Vsolution

Vol. depends on Temp. and Molarity depends on Temp.

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Statement - I : One molar aqueous solution (d=1gm/cc) has always higher concentration than one molal.Statement - II : The molality of a solution does not depends on temperature whereas molarity depends