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Q.

Statement - I : Oxidation of 1° alcohols with anhydrous CrO3 will gives aldehydes but not carboxylic acids
Statement - II : Anhydrous CrO3 is a mild oxidant

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is A.

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Detailed Solution

  • Primary alcohols are oxidized to aldehydes. Aldehydes are further oxidized to carboxylic acids.
    CH3​−CH2​−OH+[O] CrO3 CH3​−CHO + H2​O
    CH3​−CHO + [O]​​CrO3CH3​−COOH
  • Anhydrous CrO3 is a mild oxidant. 
  • Mild oxidants oxidizes Aldehydes to carboxylic acids.
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Statement - I : Oxidation of 1° alcohols with anhydrous CrO3 will gives aldehydes but not carboxylic acidsStatement - II : Anhydrous CrO3 is a mild oxidant