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Q.

Statement - I : (Ph3P)3 RhCl is Wilkinson’s catalyst.
Statement - II : (Ph3P)3RhCl can show optical isomerism but does not show geometrical isomerism.

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is C.

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Detailed Solution

(Ph3P)3 RhCl is Wilkinson’s catalyst used for hydrogenation of alkenes. 

(Ph3P)3 RhCl is a square planar complex with one arrangement so, doesn't show optical and geometrical isomerism

therefore statement 1 is correct and statement 2 is incorrect

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Statement - I : (Ph3P)3 RhCl is Wilkinson’s catalyst.Statement - II : (Ph3P)3RhCl can show optical isomerism but does not show geometrical isomerism.