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Q.

Statement - I : The geometrical isomers of the complex [M(NH3)4Cl2] are optically inactive
Statement - II : Both geometrical isomers of the complex [M(NH3)4Cl2] possess axis of symmetry

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is A.

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Detailed Solution

  • For a complex to be optically active, it should not possess either center of symmetry or axis of symmetry or plane of symmetry. 
  • Here, the given complex is an octahedral complex  that possesses plane of symmetry as well as axis of symmetry and thus is optically inactive.      
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