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Q.

Statement - I : The hydrolysis of XeF6 is not a redox reaction
Statement - II : XeF6 on complete hydrolysis will give XeO3

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a

Both statements I and II are correct

b

Statement-I is correct and statement-II is incorrect

c

Statement-I is incorrect and statement-II is correct

d

Both statements I and II are incorrect

answer is B.

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Detailed Solution

Statement I is correct. The hydrolysis of XeF6 is not a redox reaction.

During the hydrolysis of XeF6, water molecules react with the fluoride ions in XeF6 to form HF and HXeOF5. The oxidation state of xenon in XeF6 is +6, and in HXeOF5, it is +4. However, the oxidation state of xenon does not change during this reaction, so it is not a redox reaction.

Statement II is incorrect. XeF6 on complete hydrolysis does not give XeO3. XeF6 can undergo partial or complete hydrolysis to form various compounds depending on the conditions.

Complete hydrolysis of XeF6 with excess water can produce XeO3 and XeOF4, as shown in the following reaction:

XeF6 + 3H2O → XeO3 + 2XeOF4 + 6HF

Therefore, Statement I is correct, but Statement II is incorrect.

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