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Q.

Statement - I: Aq. CuSO4 on electrolysis using Pt electrodes gives Cu at cathode and O2 at anode

Statement - II : Aq. CuSO4on electrolysis using Cu electrodes gives Cu at cathode and  Cu+2 ions at anode

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a

If both statements, I and II, are correct.

 

b

If both statements, I and statement II, are incorrect.

 

c

If statement I correct, but statement II is incorrect.

 

d

If statement I incorrect, but statement II is correct.

answer is A.

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Detailed Solution

In presence of inert electrode SRP of Cu > SRP of H2O. Thus Cu+2 is reduced to Cu at cathode

In presence of attackable electrode metal electrode itself undergoes oxidation at anode, Cu is oxidised to form Cu+2

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