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Q.

Statement - I :Cu+2(aq) is more stable than Cu+(aq)
Statement - II :Heat of hydration of Cu+2 is more than IP2 of Cu

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is A.

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Detailed Solution

Half filled and completely filled subshells are more stable.
However Cu2+ with 3d9 electronic configuration is more stable than Cu+ with 3d10 electronic configuration.
This is because electrode potential is more significant in determining stable oxidation state than electronic configuration.
The standard electrode potential for Cu2+/Cu is lower than the standard electrode potential for Cu+/Cu

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