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Q.

Statement - I: In many crystal structures of ionic substances cations occupy the voids created by anions.
Statement - II: Cations are smaller than anions.

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is A.

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Detailed Solution

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  • Ionic compounds are made up of anions and cations. 
  • Usually, the larger anions make up the framework of the crystal lattice and the smaller cations then occupy the spaces or holes left between the framework of anions.
  • Cation are smaller & anions larger in radii than their parent atoms because, there is a loss of electrons from valence shell in the case of cation, so it decreases the shell number and in the case of anion, there is addition of electrons, which causes a decrease in size of cation and increases the size of anion.
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