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Q.

Statement - I :In PCl5 axial P–Cl bonds are weaker than equatorial P–Cl bonds.
Statement - II :In PCl5 axial P–Cl bonds experience greater repulsion from equatorial P–Cl bonds than the repulsion among equatorial P–Cl bonds.

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a

Both statements I and II are correct

b

Statement-I is incorrect and statement-II is correct

c

Both statements I and II are incorrect

d

Statement-I is correct and statement-II is incorrect

answer is A.

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Detailed Solution

There are two types of bonds in PCl5, axial and equatorial bonds.

The bond length of the axial bond is longer than the equatorial bond because the axial bond experiences more repulsion than the equatorial bond. This makes the axial bond relatively weaker than the equatorial bond.

Hence, both statements I and II are correct.

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