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Statement - I :In PF₅, ‘P’ has two types of P – F bond lengths
Statement - II :In PF₅, ‘P’ undergoes sp³d hybridization with trigonal bipyramidal structure and possess unequal bond angles and bond lengths.

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Both statements I and II are correct

Statement-I is incorrect and statement-II is correct

Both statements I and II are incorrect

Statement-I is correct and statement-II is incorrect

answer is A.

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Detailed Solution

PF₅ has three axial bonds and two equatorial bonds, PF₅ has sp³d hybridization. In PF₅, two Cl atoms lie along axial line and other three Cl atoms lie along the equatorial plane.

Hence, Cl atoms which lie along axis have different bond length than that of Cl atoms lying on equatorial plane.

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