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Q.

Statement -I: Potassium ferrocyanide is diamagnetic whereas potassium ferricyanide is paramagnetic 
Statement -II: Crystal field splitting in ferrocyanide ion is greater than that of ferricyanide ion
 

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a

Both statements I and II are false

b

Both statements I and II are correct

c

Statement I is correct II is false

d

Statement I is false II is correct

answer is B.

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Detailed Solution

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Potassium ferrocyanide is diamagnetic whereas potassium ferricyanide is paramagnetic 
Crystal field splitting in ferrocyanide ion is lower than that of ferricyanide ion 

crystal field splitting  charge on the metal ion  

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