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Q.

Statement 1 : At low pressure van der Waals' equation is reduced to P+aV2V=RT.

Statement 2 : The compressibility factor corresponding to low pressure is given by :

                                      1-RTVa.

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a

Both Statement 1 and Statement 2 are true.

b

Both Statement 1 and Statement 2 are false.

c

Statement 1 is false and Statement 2 is true.

d

 Statement 1 is true and Statement 2 is false.            

answer is B.

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Detailed Solution

PV+aV=RT   PV = RT -aV; Thus, Z = PVRT=1-aRTV

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