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Q.

Statement 1 : Boron always forms covalent bond 

Statement 2 : The small size of B3+ favors for the formation of covalent bond.

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a

Statement 1 is true and Statement 2 is true. Statement 2 is a correct explanation for the statement 1

b

Statement 1 is true and Statement 2 is false 

c

Statement 1 is false and Statement 2 is true 

d

Statement 1 is true and Statement 2 is true. Statement 2 is not the correct explanation for statement 1

answer is A.

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Detailed Solution

  • Boron is the first element of the group-13 and has the smallest size.
  •  Ionization energy is the energy required for the removal of a valence electron from an isolated gaseous atom.
  •  Formation of B3+ from boron required very high ionization energy. 
  • Therefore, boron is more susceptible to form covalent bond than ionic bond.
  • Furthermore, size of B3+ is extremely small and a high charge density. 
  • Considering Fajan's rule, boron has the maximum covalent character in the bond.
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