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Q.

Statement 1 : Carbon has unique ability to form  multiple bonds with itself and with other atoms of small size and high electronegativity.

Statement 2 : Heavier elements of group 14th do not form  bonds because their atomic orbitals are to large and diffuse to have effective sideways overlapping.

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a

Both Statement 1 and Statement 2 are true.

b

 Statement 1 is true and Statement 2 is false.

c

Statement 1 is false and Statement 2 is true.

d

Both Statement 1 and Statement 2 are false.

answer is A.

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Detailed Solution

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Both statements are true.

 Atomic size of carbon is smaller and thus it has effective overlapping with itself and with other atoms of small size and high electronegativity. Few examples of multiple bonding are C=C,  CC,  C=O,C=S  and  CN. Heavier elements do not form  bonds because their atomic orbitals are too large and diffuse to have effective overlapping.

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