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Q.

Statement 1 : Elemental nitrogen exists as a diatomic molecule and phosphorous as tetratomic molecule.

Statement 2 : Nitrogen does not have vacant d-orbital whereas phosphorus have vacant d-orbital.

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a

 Statement 1 is false and Statement 2 is true.

b

 Statement 1 is true and Statement 2 is false.

c

Both Statement 1 and Statement 2 are false.

d

Both Statement 1 and Statement 2 are true .

answer is A.

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Detailed Solution

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Elemental nitrogen exists as a diatomic molecule because nitrogen can form multiple bonds which is not possible in case of phosphorus due to repulsion between non-bonded electrons of the inner core. There is no such repulsion in case of smaller nitrogen atoms as they have only 1s2 electrons in their inner core.

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Statement 1 : Elemental nitrogen exists as a diatomic molecule and phosphorous as tetratomic molecule.Statement 2 : Nitrogen does not have vacant d-orbital whereas phosphorus have vacant d-orbital.