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Q.

Statement-1 : Native Ag and Ag2S are dissolved in CN solution in presence of Air (O2).

 

Statement-2 : Air (O2) acts as oxidant for Ag  and Ag2S both.

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a

Statement-1 is false, statement-2 is true.

b

Statement-1 is true, statement-2 is false.

c

Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.

d

Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.

answer is C.

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Detailed Solution

Ag2S + 4NaCN air/O2 2na[Ag(CN)2 ] + Na2S

Role of air/O2 is to oxidize Na2S  to proceed reaction forward.

2Ag + 4naCN + H2O +12 O2 ˥ 2Na[Ag(CN)2  ] + 2NaOH

Native ore Role of air/O2 is to oxidize Ag noble metal into Ag+

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