Statement 1 : Order of basicity of amines in gaseous phase is NH₃ > primary amine>secondary amine > tertiary amine.
Statement 2 : In gaseous phase the basic nature of aliphatic amine increases with the increase in number of alkyl groups.

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Both statements 1 and 2 are correct

Both statements 1 and 2 are incorrect

Statement 1 is incorrect and statement 2 is correct

Statement 1 is correct and statement 2 is incorrect

answer is D.

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Detailed Solution

Order of basicity of amines in gaseous phase follows the order:
Tertiary amine > secondary amine > primary amine > NH₃ The basic nature of aliphatic amines increases with increase in the number of alkyl groups (in gaseous phase).

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