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Q.

Statement-1 : The geometrical isomers of the complex [M(NH3)4Cl2] are optically inactive.

Statement-2 : Both geometrical isomers of the complex [M(NH3)4Cl2] possess axis of symmetry.

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a

Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.

b

Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.

c

Statement-1 is true, statement-2 is false.

d

Statement-1 is false, statement-2 is true.

answer is B.

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Detailed Solution

Ma4b2 have two geometrical isomers which have plane of symmetry, so does not show optical isomerism. Optically inactive compounds may contain axis of symmetry.

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