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Q.

Statement 1 : The intense blue colour of prussion blue and turnbull’s blue is due to electron transfer between Fe(II) and Fe (III) present in these compounds
Statement 2 : Prussion blue and turnbull’s blue differ in the oxidation states of iron inside and outside of the coordination sphere of the compounds

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a

Statement -1 is true, statement -2 is false.

b

Statement -1 is false, Statement -2 is true

c

Statement -1 is true, statement -2 is true; statement -2 is the correct explanation for statement -1.

d

Statement -1 is true, statement -2 is true; statement -2 is NOT the correct explanation for statement -1.

answer is A.

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Detailed Solution

The intense blue colour is due to charge transfer between Fe(II) and Fe(III) in out but side of the coordination sphere.

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Statement 1 : The intense blue colour of prussion blue and turnbull’s blue is due to electron transfer between Fe(II) and Fe (III) present in these compoundsStatement 2 : Prussion blue and turnbull’s blue differ in the oxidation states of iron inside and outside of the coordination sphere of the compounds