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Q.

Statement 1 : To obtain effective  overlap, the size of the d-orbital must be similar to the size of the p-orbital. So for chlorine  bonding is strongest in their oxoanions.

Statement 2 : On moving a period from left to right in the periodic table, the nuclear charge is increased and more s and p-electrons are added. Since these s- and p-electrons shield the nuclear charge incompletely, the size of the atom and that of the d-orbitals decreases. This leads to progressively stronger  bonding.

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a

Both Statement 1 and Statement 2 are true.

b

 Statement 1 is true and Statement 2 is false.

c

Statement 1 is false and Statement 2 is true.

d

Both Statement 1 and statement 2 are false.

answer is A.

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Detailed Solution

Both the statements are true.

 

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pπdπ  overlap

 

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