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Q.

Statement-1 : 0 increases in the order of [CrCl6]3-<[Cr(CN)6]3-<Cr(C2O4)33-

Statement-2 : Stronger the ligand field higher will be 0 value. 

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a

Statement-1 is false, statement-2 is true.

b

Statement-1 is true, statement-2 is false.

c

Statement-1 is true, statement-2 is true and statement-2 is NOT the correct explanation for statement-1.

d

Statement-1 is true, statement-2 is true and statement-2 is correct explanation for statement-1.

answer is D.

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Detailed Solution

According to spectrochemical series CN- is stronger field ligand, so it has more 0
value, so correct order of 0 for these complex ions.

       [CrCl6]3-<[Cr(C2O4)3]3-<[Cr(CN)6]3-

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