Q.

Statement 1: 2,3-dimethyl but-2-ene is more stable than but-2-ene.

Statement 2: 2,3-dimethyl but-2-ene possesses 12 α-hydrogen atoms whereas but-2-ene possesses only 6 α-hydrogen atoms and therefore former shows more pronounced hyperconjugation.

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a

Statement 1 is correct and statement 2 is incorrect

b

Statement 1 is incorrect and statement 2 is correct

c

Both statements 1 and 2 are correct

d

Both statements 1 and 2 are incorrect

answer is A.

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Detailed Solution

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The phenomenon of displacement of electrons by conjugative mechanism involving -σ and π-electron is called hyperconjugation. It happens when alkyl groups having at least one of the α-carbon atoms attached to an unsaturated carbon atom is able to release electrons due to delocalization of -σ and π-bond. It is more pronounced as α-H atoms are more in number. Thus, stability of alkenes has been explained in terms  of hyperconjugation.

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