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Q.

Statement-1: A tertiary butyl carbocation is more stable than a secondary butyl carbocation. 
Statement-2: Hyperconjugation shown by tertiary butyl carbocation as it has 9αH atoms

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a

Statement-1 and Statement-2 both are correct, Statement-2   is not explanation of Statement-1  

b

Statement-1 is correct, Statement-2 is wrong.

c

Statement-1 is incorrect, Statement-2 is correct.

d

Statement-1 and Statement-2 both are correct, Statement-2 is correct explanation of Statement-1

answer is A.

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Detailed Solution

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In tertiary carbocation, there are nine hyperconjugation structures, whereas, in secondary carbocation, there are only six. Thus, tertiary carbocation is more stable than secondary carbocation, according to the Hyperconjugation effect. As a result, tertiary carbocation is more stable than secondary carbocation.

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Statement-1: A tertiary butyl carbocation is more stable than a secondary butyl carbocation. Statement-2: Hyperconjugation shown by tertiary butyl carbocation as it has 9α−H atoms