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Q.

Statement-1 : Acetone + Carbon disulphide solution shows positive deviation from Raoult’s law
Statement-2 : Acetone + Aniline solution shows positive deviation from Raoult’s law

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a

Both statement-1 and statement-2- are wrong

b

Statement-1 is correct and statement-2 is wrong

c

Statement-1 is wrong and statement-2 is correct

d

Both statement-1 and statement-2- are correct

answer is C.

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Detailed Solution

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Acetone - Carbon disulphide solution shows a positive deviation from Raoult's law. The observed vapour pressure of each component and total vapour pressure is greater than predicted by Raoult's law.

Acetone + Aniline solution shows a negative deviation from Raoult's law. The observed vapour pressure of each component and total vapour pressure is less than predicted by Raoult's law.

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Statement-1 : Acetone + Carbon disulphide solution shows positive deviation from Raoult’s lawStatement-2 : Acetone + Aniline solution shows positive deviation from Raoult’s law