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Q.

Statement 1: Acetylene on reacting with sodamide gives sodium acetylide and ammonia.

Statement 2: sp-hybridised carbon atoms of acetylene are considerably electronegative.

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a

Statement 1 is correct and statement 2 is incorrect

b

Statement 1 is incorrect and statement 2 is correct

c

Both statements 1 and 2 are correct

d

Both statements 1 and 2 are incorrect

answer is A.

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Detailed Solution

Acetylene on reaction with sodamide gives sodium acetylide and ammonia.

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Here formation of sodium acetylide can be explained by 'sp' hybridization of carbon atom. As we know that an electron in s-orbital is more tightly held than in a p-orbital. ln ‘sp’ hybridization, s-character is 50% as compared to sp2 (33% ) or sp3(25%). So, due to large s-character the carbon atom is quite electronegative and hence Na of NaNH2 can replace H+ of C-H bond. Hence statement 1 and statement 2 both are true and statement 2 is the  explanation of statement 1.

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Statement 1: Acetylene on reacting with sodamide gives sodium acetylide and ammonia.Statement 2: sp-hybridised carbon atoms of acetylene are considerably electronegative.