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Q.

Statement 1 : Al3+ forms more ionic compound in comparison to Ga3+, with identical anion.

Statement 2 : rAl3+    rGa3+  and  zeff  ofGa3+ is more than that of Al3+.

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a

 Statement 1 is false and Statement 2 is true.

b

 Statement 1 is true and Statement 2 is false.

c

Both Statement 1 and Statement 2 are false.

d

Both Statement 1 and Statement 2 are true .

answer is A.

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Detailed Solution

Due to poor shielding by d-electrons in Ga3+,  its  Zeff is more. So its polarizing power is more and hence it forms compound with higher covalent character.

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