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Q.

Statement-1: Aluminium chloride in acidified aqueous solution forms octahedral AlH2O63+ ion. 

Statement-2: In AlH2O63+ complex ion, the 3d orbitals of Al are involved and the hybridization state of Al is sp3d2

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a

Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.

b

Statement-1 is False, Statement-2 is True

c

Statement-1 is True, Statement-2 is True, Statement-2 Is NOT a correct explanation for Statement-1.

d

Statement-1 is True, Statement-2 is False.

answer is A.

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Detailed Solution

"Aluminum chloride in acidified aqueous solution forms octahedral AlH2O63+ ion" is correct In Because in aqueous solution, aluminum chloride forms a complex with aluminum as a metal atom and water as a ligand. Six ligands are present. As a result, it is an octahedral complex, and the hybridization involved is [sp3d2], indicating that it is an outer orbital complex.

Both are valid, and Statement 2 explains Assertion correctly. AlH2O63+.

So, Aluminum is in the +3 oxidation state in 

AlH2O63+

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