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Q.

Statement-1: Carbon bas unique ability to form pπ-pπ multiple bonds with itself and with other atoms of small size and high electronegativity. 

Statement-2: Heavier elements of group 14th do not form pπ-dπ bonds because their atomic orbitals are too large and diffused to have effective side ways overlapping.

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a

Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1

b

Statement-1 is True, Statement-2 is True, Statement-2 Is NOT a correct explanation for Statement-1.

c

Statement-1 is True, Statement-2 is False.

d

Statement-1 is False, Statement-2 is True

answer is B.

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Detailed Solution

S-1 and S-2 are both true assertions, but they are not the same, and reason is not a true explanation of the claim. 

Because the high electronegativity of atoms linked to carbon leads in the shrinkage of the size of p-orbitals and the carbon atomic size is lower, it has effective overlapping.

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