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Q.

Statement 1 :Carbon has unique ability to form pπpπ multiple bonds with itself and

                    with other atoms of small size and high electronegativity

Statement 2 : Heavier elements of group 14th do not form pπpπ multiple bonds with itself 

                      because their atomic orbitals are too large and diffuse to have effective overlapping

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a

Statement 1 is true, statement 2 is true: statement 2 is not a correct explanation for statement 1

b

Statement 1 is false. statement 2 is true

c

Statement 1 is true, statement 2 is true; statement 2 is a correct explanation for statement 1 

d

Statement 1 is true, statement 2 is false

answer is B.

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Detailed Solution

Both S-1 and S- 2 are true statements but are different and

 statements-2 is not true explanation of 

statements-1. High electronegativity of atoms attached to carbon atom indirectly

 results into the contraction of the size of p-orbitals.

 As carbon atomic size is smaller and thus it has effective overlapping.

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