Q.

Statement 1: Chlorobenzene and Benzyl halide are homologues 

Statement 2: Chlorobenzene and o-chlorotoluidine are homologues 

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a

Statement 1 is incorrect statement 2 is correct

b

Statement 1 is correct statement 2 is incorrect

c

Both statements 1 and 2 are correct

d

Both statements 1 and 2 are incorrect

answer is C.

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Detailed Solution

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(1) & (2) differ by a CH2gp and belong to same Homologous series

 Homologues 

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Though (1) & (3) differ by CH2group, but Cl attached to different hybridised carbon atoms, so  they don't belongs to same Homologues series. They are not homologues

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Statement 1: Chlorobenzene and Benzyl halide are homologues Statement 2: Chlorobenzene and o-chlorotoluidine are homologues