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Q.

Statement 1: Coordination number of CsCl changes from 8 : 8 to 6 : 6 on heating.

Statement 2: The crystal structure of CsCl changes to NaCl on heating.

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a

Both Statement 1 and Statement 2 are true.

b

Statement 1 is true but Statement 2 is false.

c

Both Statement 1 and Statement 2 are false.

d

Statement 1 is false but Statement 2 is true.

answer is A.

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Detailed Solution

CsCl has B.C.C. structure at room temperature with co-ordination number 8.on heating its co-ordination number decreases and becomes 6 and thus acquires rock .salt structure.(F.C.C)

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Statement 1: Coordination number of CsCl changes from 8 : 8 to 6 : 6 on heating.Statement 2: The crystal structure of CsCl changes to NaCl on heating.