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Q.

Statement-1 : Cu(OH)2 is soluble in excess NH4OH(aq.) but not soluble in excess NaOH(aq.) but reverse is true for  Al(OH)3.
Statement-2 : Al(OH)3  is amphoteric  but Cu(OH)2 is basic

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a

Statement-1 is False, Statement-2 is True.

b

Statement -1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1

c

Statement-1 is True, Statement-2 is False 

d

Statement -1 is True, Statement-2 is True; Statement-2 is a NOT correct explanation for Statement-1.

answer is B.

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Detailed Solution

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Al(OH)3= Amphoteric hydroxide
Cu(OH)2=Basic hydroxide 

Al(OH)3+NaOH  NaAlO2 (soluble)+ 2H2O Cu(OH)2+4NH4OH (Cu(NH3)4)(OH)2soluble complex+4H2O

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Statement-1 : Cu(OH)2 is soluble in excess NH4OH(aq.) but not soluble in excess NaOH(aq.) but reverse is true for  Al(OH)3.Statement-2 : Al(OH)3  is amphoteric  but Cu(OH)2 is basic