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Q.

Statement 1 :  Cu2+andCd2+ are separated by first adding KCN solution and then passing H2S gas

Statement 2: KCN reduces Cu2+ to Cu+  and form a complex with it

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a

Statement-I is true, statement -2 is true; statement-2 is a correct explanation for statement -1

b

Statement -1 is true, statement-2 is true; statement-2 is NOT a correct explanation for statement -1

c

 Statement -1 is true, statement -2 is false

d

Statement-1 is false, statement-2 is true

answer is B.

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Detailed Solution

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The correct explanation of assertion is KCN from complex with Cu+and  Cd2+as 

K3CuCN4 and K2CdCN4 respectively. On passing H2S, only Cd2+complex gives yellow cds ppt.

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