Q.

Statement 1: Esters which contain α-hydrogens undergo Claisen condensation.

Statement 2: LiAlH4 reduction of esters gives acids.

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a

Statement 1 is correct and statement 2 is incorrect

b

Statement 1 is incorrect and statement 2 is correct

c

Both statements 1 and 2 are incorrect

d

Both statements 1 and 2 are correct

answer is B.

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Detailed Solution

It is known that esters with α-hydrogens form carbanion when treated with base. It bring about nucleophilic substitution at the carbonyl group of the other molecules of the ester to yield p-keto ester. LiAlH4 reduces esters to alcohols.

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Statement 1: Esters which contain α-hydrogens undergo Claisen condensation.Statement 2: LiAlH4 reduction of esters gives acids.