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Q.

Statement-1: Fluorine has a less negative electron gain enthalpy than chlorine.

Statement-2: There is relative greater effectiveness, of 2p-electron in the small F atom to repel the additional electron entering the atom than to Sp-electrons in the larger Cl atom.

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a

 Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.

b

Statement-1 is True, Statement-2 is False.

c

Statement-1 is False, Statement-2 is True.

 

d

 Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1.

 

answer is A.

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Detailed Solution

The little Fatom's 2p electrons are more effective at repelling the extra electron than the larger Cl atom's 3p electrons are at doing the same. As a result, fluorine has a lower affinity for negatively charged electrons than chlorine. As a result, both the claim and the reason are true, and the reason provides a valid justification for the assertion.

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