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Q.

Statement 1: Freezing point of solvent is more than that of solution.
Statement 2: When non-volatile solid is added to the solvent, its vapour pressure increases and become equal to solid solvent at the lower temperature.
 

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a

Statement 1 is incorrect statement 2 is correct

b

Both statements 1 and 2 are correct

c

Statement 1 is correct statement 2 is incorrect

d

Both statements 1 and 2 are incorrect

answer is C.

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Detailed Solution

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At the free zing point, the solid phase of a substance is in dynamic equilibrium with its liquid phase. A solution will freeze, when its vapour pressure becomes equals to the vapour pressure of the pure solid solvent.
When non-volatile solid is added to the solvent, its vapour pressure decreases and becomes equal to solid solvent at lower temperature.
Freezing point of the solvent is more than that of solution.

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Statement 1: Freezing point of solvent is more than that of solution.Statement 2: When non-volatile solid is added to the solvent, its vapour pressure increases and become equal to solid solvent at the lower temperature.