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Q.

Statement-1: In neutral solution, there is partial precipitation of zinc sulphide by hydrogen sulphide gas. 

Statement-2: The complete precipitation of zinc sulphide takes place by hydrogen sulphide gas when alkali metal acetate is added to the solution.

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a

Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.

b

Statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1.

c

Statement-1 is True, Statement-2 is False.

d

Statement-1 is False, Statement-2 is True.

answer is B.

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Detailed Solution

ZnS partial ppt. occurs in neutral solutions due to  S2-ion conc. Derived from H2S is too severely reduced [H+] Acid, preventing Ksp of ZnS from being significantly surpassed. By eliminating [H+](Acid) alkali solutions raise  [S2-)],which increaseses the zinc sulphite precipitate. So,statement-1 is True, Statement-2 is True, Statement-2 is NOT a correct explanation for Statement-1.Hence, option B is correct.

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