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Q.

Statement-1: In IOF4- a single lone pair is present on iodine atom trans to oxygen atom to have minimum repulsion between the I = O and the lone pair of electrons.

Statement-2: The VSEPR model considers double and triple bonds to have slightly greater repulsive effect than single bonds because of the repulsive effect of π electrons

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a

Statement-1 is True, Statement-2 is True; Statement-2 is a correct explanation for Statement-1.

b

Statement-1 is False, Statement-2 is True

c

Statement-1 is True, Statement-2 is True, Statement-2 Is NOT a correct explanation for Statement-1.

d

Statement-1 is True, Statement-2 is False.

answer is A.

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Detailed Solution

Statement 1: In order to have the least amount of repulsion between the I=O and the lone pair of electrons (a stronger replusion effect), the lone pair should be opposite the I=O bond.

Statement 2 : Correct Statement.

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