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Q.

Statement-1: Initially there is no ppt. when  AgNO3 is added to Na2SO3 solution.

Statement-2: Localized formation of Ag2SO3 is destroyed by soluble complex formation like AgSO3.

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a

Both (A) and (R) are true but (R) is not the correct explanation of (A)

b

Both (A) and (R) are true and (R) is the correct explanation of (A)

c

Both (A) and (R) are false

d

(A) is true but (R) is false

answer is A.

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Detailed Solution

When  AgNO3 is introduced to Na2SO3 solution, there is initially no ppt because localized  AgNO3 formation is shattered by the creation of soluble complexes such AgNO3.

Hence, option A is correct.

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Statement-1: Initially there is no ppt. when  AgNO3 is added to Na2SO3 solution.Statement-2: Localized formation of Ag2SO3 is destroyed by soluble complex formation like AgSO3−.